Job Level can be raised by spending materials: faint memories, statues, elemental crystals, weapon crystals, and job memories.
By leveling up, units' stats are enhanced and more panels on the ability bords get ready to be unlocked with spending Job Points.
Here is a list of required materials for each job level.
MR Units & MR Tier List
Cloud (FFVIIR)
SR Units & SR Tier List
Gil Guilde: Gil Snapper, Gil Farming, What to Spend Gil On
Guild Recruitment Forum
Kotetsu
Shuriken